| Date | Opponent | Location | Time/Recap |
| 08/25/06 | Florida State 3, Mississippi Valley State 0 | Macon, Ga. | Recap |
| | Davidson 3, NC State 0 | Charlotte, N.C. (Spring Hill Suites Classic) | Recap |
| | Virginia Tech 3, Furman 1 | Greenville, N.C. (East Carolina Tournament) | Recap |
| | Clemson 3, Bradley 0 | West Lafayette, IN (Mortar Board Premier) | Recap | Gametracker |
| | North Carolina 3, Idaho 0 | Norman, Okla. (Sooner Legends Nike Invitational) | Recap |
| | Florida State 3, Mercer 0 | Macon, Ga. | Recap |
| | Duke 3, Marquette 1 | Durham, N.C. (Duke Invitational) | Recap |
| | Miami 3, Alabama 2 | Tuscaloosa, Ala. (Academy Sports Invitational) | Recap |
| | Tennessee Women 3, Virginia 1 | Knoxville, Tenn. (Comcast Lady Vol Classic) | Recap | Gametracker |
| 08/26/06 | Duke 3, Gardner-Webb 0 | Durham, N.C. (Duke Invitational) | Recap |
| | Virginia 3, Miami (OH) 0 | Knoxville, Tenn. (Comcast Lady Vol Classic) | Recap | Gametracker |
| | Virginia Tech 3, William & Mary 0 | Greenville, N.C. (East Carolina Tournament) | Recap |
| | Kansas 3, Miami 1 | Tuscaloosa, Ala. (Academy Sports Invitational) | Recap |
| | Northern Iowa 3, Clemson 2 | West Lafayette, IN (Mortar Board Premier) | Recap | Gametracker |
| | ETSU 3, NC State 1 | Charlotte, N.C. (Spring Hill Suites Classic) | Recap |
| | Arkansas 3, North Carolina 0 | Norman, Okla. (Sooner Legends Nike Invitational) | Recap |
| | Miami 3, Alabama A&M 0 | Tuscaloosa, Ala. (Academy Sports Invitational) | Recap |
| | Virginia 3, Centenary 0 | Knoxville, Tenn. (Comcast Lady Vol Classic) | Recap | Gametracker |
| | Duke 3, VCU 0 | Durham, N.C. (Duke Invitational) | Recap |
| | Oklahoma 3, North Carolina 0 | Norman, Okla. (Sooner Legend Nike Invitational) | Recap |
| | Purdue 3, Clemson 1 | West Lafayette, IN (Mortar Board Premier) | Recap | Gametracker |
| | Virginia Tech 3, East Carolina 0 | Greenville, N.C. (East Carolina Tournament) | Gametracker | Recap |
| | Charlotte 3, NC State 0 | Charlotte, N.C. (Spring Hill Suites Classic) | Recap |
| 08/31/06 | South Carolina 3, Clemson 2 | Clemson, SC (Big Orange Bash) | Recap | Gametracker |
| 09/01/06 | Clemson 3, Western Carolina 0 | Clemson, SC (Big Orange Bash) | Recap | Gametracker |
| | Mississippi State 3, Georgia Tech 1 | Atlanta, Ga. (Regency Suites Midtown Invitational) | Recap | Gametracker |
| | Eastern Michigan 3, Miami 0 | East Lansing, Mich. (Michigan State Tournament) | Recap |
| | Maryland 3, Chicago State 0 | Bloomington, IN (IU Classic) | Recap |
| | Purdue 3, Virginia Tech 1 | Auburn, Ala. (Auburn/Mizuno Challenge) | Recap |
| | Belmont 3, Boston College 2 | Oxford, OH (Miami-Ohio Tournament) | Gametracker | Recap |
| | Duke 3, West Virginia 0 | University Park, Penn. (Penn State Invitational) | Gametracker | Recap |
| | Utah 3, North Carolina 0 | Los Angeles, Calif. (Loyola Marymount Tournament) | Recap |
| | Georgia Tech 3, Georgia 2 | Atlanta, Ga. (Regency Suites Midtown Invitational) | Recap |
| | Colorado State 3, Wake Forest 0 | Fort Collins, Colo. (Colorado State Tournament) | Recap |
| | Florida State 3, Stetson 0 | Tallahassee, Fla. (FSU Invitational) | Recap | Gametracker | Webcast |
| | Virginia 3, Georgetown 0 | Charlottesville, Va. (Jefferson Cup Volleyball Tournament) | Recap | Gametracker |
| | Winthrop 3, NC State 1 | Raleigh, N.C. (Wolfpack Classic) | Recap |
| | Clemson 3, Tennessee State 0 | Clemson, SC (Big Orange Bash) | Recap | Gametracker |
| 09/02/06 | Georgia Tech 3, Georgia State 0 | Atlanta, Ga. (Regency Suites Midtown Invitational) | Recap | Gametracker |
| | Florida State 3, South Alabama 0 | Tallahassee, Fla. (FSU Invitational) | Recap | Gametracker |
| | Maryland 3, Marshall 1 | Bloomington, IN (IU Classic) | Recap |
| | Wake Forest 3, James Madison 0 | Fort Collins, Colo. (Colorado State Tournament) | Recap | Gametracker |
| | Western Kentucky 3, Boston College 0 | Oxford, OH (Miami-Ohio Tournament) | Recap |
| | Villanova 3, Miami 2 | East Lansing, Mich. (Michigan State Tournament) | Recap |
| | Virginia 3, Wright State 0 | Charlottesville, Va. (Jefferson Cup Volleyball Tournament) | Recap | Gametracker |
| | Auburn 3, Virginia Tech 2 | Auburn, Alabama (Auburn/Mizuno Challenge) | Recap |
| | NC State 3, Chattanooga 0 | Raleigh, N.C. (Wolfpack Classic) | Recap |
| | Clemson 3, Charlotte 1 | Clemson, SC (Big Orange Bash) | Recap | Gametracker |
| | Duke 3, Eastern Kentucky 0 | State College, Penn. (Penn State Invitational) | Gametracker | Recap |
| | Tennessee 3, North Carolina 0 | Los Angeles, Calif. (Loyola Marymount Tournament) | Recap |
| | Georgia Tech 3, Northern Iowa 2 | Atlanta, Ga. (Regency Suites Midtown Invitational) | Recap | Gametracker |
| | Wake Forest 3, Florida Atlantic 0 | Fort Collins, Colo. (Colorado State Tournament) | Recap | Gametracker |
| | Arizona State 3, Virginia Tech 0 | Auburn, Ala. (Auburn/Mizuno Challenge) | Recap |
| | Florida State 3, Eastern Illinois 0 | Tallahassee, Fla. (FSU Invitational) | Recap | Gametracker |
| | Maryland 3, Indiana 2 | Bloomington, Ind. (IU Classic) | Recap |
| | Miami (Ohio) 3, Boston College 2 | Oxford, OH (Miami-Ohio Tournament) | Gametracker |
| | Michigan State 3, Miami 0 | East Lansing, Mich. (Michigan State Tournament) | Recap |
| | Northern Colorado 3, NC State 1 | Raleigh, N.C. (Wolfpack Classic) | Recap |
| | Virginia 3, East Carolina 1 | Charlottesville, Va. (Jefferson Cup Volleyball Tournament) | Recap | Gametracker |
| | Penn State 3, Duke 0 | State College, Pa. (Penn State Invitational) | Gametracker | Recap |
| | Loyola Marymount 3, North Carolina 1 | Los Angeles, CA (Loyola Marymount Tournament) | Recap | Gametracker |
| 09/08/06 | Georgia Tech 3, Villanova 1 | Lexington, KY (Kentucky Classic) | Recap |
| | Maryland 3, Albany 0 | Long Island, NY (Stony Brook Invitational) | Recap | Gametracker |
| | USC 3, Florida State 0 | Columbia, SC (South Carolina Tournament) | Recap | Gametracker |
| | Virginia 3, Pacific 1 | Ann Arbor, Mich. (Michigan/Pepsi Challenge) | Recap | Gametracker |
| | Ohio 3, Maryland 1 | Long Island, NY (Stony Brook Invitational) | Recap | Gametracker |
| | Indiana 3, Wake Forest 2 | Dayton, Ohio (Mariott Flyer Invitational) | Recap | Gametracker |
| | Georgia Tech 3, Toledo 1 | Lexington, KY (Kentucky Classic) | Recap |
| | NC State 3, Chicago State 1 | Kent, Ohio (KSU Invitational) | Recap |
| | St. John's 3, Florida State 1 | Columbia, SC (South Carolina Tournament) | Recap |
| | Illinois 3, North Carolina 0 | Glaxo Smith Kline UNC Volleyball Classic, Chapel Hill, N.C. | Recap | Gametracker |
| | Virginia Tech 3, George Washington 0 | Blacksburg, VA (Hokie Invitational) | Recap |
| | Connecticut 3, Boston College 2 | Storrs, Conn. (Connecticut Tournament) | Recap |
| | Michigan 3, Virginia 0 | Ann Arbor, Mich. (Michigan/Pepsi Challenge) | Recap | Gametracker |
| 09/09/06 | Northern Illinois 3, Boston College 0 | Storrs, Conn. (Connecticut Tournament) | Recap |
| | Dayton 3, Wake Forest 0 | Dayton, Ohio (Mariott Flyer Invitational) | Recap |
| | College Of Charleston 3, North Carolina 1 | Chapel Hill, N.C. (GlaxoSmithKline UNC Volleyball Classic) | Recap | Gametracker |
| | Virginia 3, Marquette 0 | Ann Arbor, Mich. (Michigan/Pepsi Challenge) | Recap | Gametracker |
| | Virginia Tech 3, Liberty 1 | Blacksburg, Va. (Hokie Invitational) | Recap |
| | Murray State 3, NC State 0 | Kent, Ohio (Kent State Invitational) | Recap |
| | Florida State 3, South Carolina 2 | Columbia, S.C. (South Carolina Tournament) | Recap | Gametracker |
| | Boston College 3, Quinnipiac 0 | Storrs, Conn. (UConn Toyota Classic) | Recap |
| | Kentucky 3, Georgia Tech 1 | Lexington, KY (Kentucky Classic) | Recap |
| | LSU 3, Wake Forest 0 | Dayton, Ohio (Mariott Flyer Invitational) | Recap | Gametracker |
| | Maryland 3, Stony Brook 2 | Long Island, NY (Stony Brook Invitational) | Recap | Gametracker |
| | North Carolina 3, Wichita State 2 | Chapel Hill, N.C. (GlaxoSmithKline UNC Volleyball Classic) | Recap | Gametracker |
| | Kent State 3, NC State 0 | Kent, Ohio (KSU Invitational) | Recap |
| | Virginia Tech 3, Appalachian State 2 | Blacksburg, Va. (Hokie Fall Invitational) | Recap |
| 09/12/06 | Florida 3, Florida State 1 | Tallahassee, Fla. on Sun Sports | Recap | Gametracker |
| 09/15/06 | Duke 3, Butler 0 | Tempe, Ariz. (Sun Devil Volleyball Classic) | Recap | Live Stats |
| | Towson 3, Boston College 0 | Ringston, R.I. (Rhode Island Tournament) | Recap |
| | FAMU 3, Miami 2 | Coral Gables, Fla. (Miami HUrrican Invitational) | Recap |
| | Maryland 3, LIU 1 | College Park, Md. (Hilton Garden Inn Greenbelt Invitational) | Recap |
| | North Carolina 3, NC State 0 | Chapel Hill, N.C. | Recap | Gametracker | Webcast |
| | Virginia Tech 3, Virginia 0 | Blacksburg, Va. | Recap | Live Stats |
| | Wake Forest 3, George Washington 2 | Winston-Salem, N.C. (Black & Gold Challenge) | Recap | Gametracker |
| | Georgia Tech 3, USF 0 | Atlanta, GA (Regency Suites Midtown Classic) | Recap | Gametracker | Webcast |
| | Duke 3, Arizona State 2 | Tempe, Ariz. (Sun Devil Volleyball Classic) | Recap |
| 09/16/06 | Maryland 3, FIU 2 | College Park, MD (Hilton Garden Inn Greenbelt Invitational) | Recap |
| | Seton Hall 3, Boston College 0 | Kingston, R.I. (Rhode Island Tournament) | Recap |
| | Georgia Tech 3, Stetson 0 | Atlanta, GA (Regency Suites Midtown Classic) | Recap | Gametracker |
| | Jacksonville 1, Miami 3 | Coral Gables, Fla. (Miami Hurricane Invitational) | Recap | Gametracker |
| | Wake Forest 3, Davidson 2 | Winston-Salem, N.C. (Black & Gold Challenge) | Recap | Gametracker |
| | Clemson 3, Furman 1 | Clemson, SC | Recap | Gametracker |
| | Boston College 3, Rhode Island 1 | Kingston, R.I. (Rhode Island Tournament) | Recap |
| | Notre Dame 3, Duke 1 | Tempe, AZ (Sun Devil Volleyball Classic) | Live Stats
|
| | Winthrop 3, Wake Forest 2 | Winston-Salem, N.C. (Black & Gold Challenge) | Recap | Gametracker |
| | Georgia Tech 3, Sam Houston State 0 | Atlanta, GA (Regency Suites Midtown Classic) | Recap | Gametracker | Webcast |
| | Loyola Marymount 3, Miami 0 | Coral Gables, FL (Miami Hurricane Invitational) | Recap | Gametracker |
| | UCLA 3, Maryland 0 | College Park, Md. (Hilton Garden Inn Greenbelt Invitational) | Recap |
| 09/19/06 | Florida State 3, Miami 2 | Miami, Fla. | Recap | Gametracker |
| 09/21/06 | Virginia Tech 3, North Carolina 0 | Blacksburg, Va. | Recap | Live Stats |
| 09/22/06 | Duke 3, Clemson 0 | Durham, NC | Recap | Live Stats |
| | Florida State 3, Maryland 0 | Tallahassee, Fl. | Recap | Gametracker | Webcast |
| | Virginia 3, North Carolina 1 | Charlottesville, Va. | Recap | Gametracker |
| | Virginia Tech 3, NC State 0 | Blacksburg, Va. | Recap | Live Stats |
| | Wake Forest 3, Georgia Tech 0 | Winston-Salem, NC | Recap | Gametracker | Webcast |
| | Boston College 3, Miami 2 | Coral Gables, Fla. | Recap | Gametracker |
| 09/23/06 | Virginia 3, NC State 1 | Charlottesville, Va. | Recap | Gametracker |
| | Clemson 3, Wake Forest 1 | Winston-Salem, NC | Recap | Gametracker |
| | Duke 3, Georgia Tech 1 | Durham, NC | Recap | Live Stats |
| 09/24/06 | Florida State 3, Boston College 1 | Tallahassee, Fla. | Recap | Gametracker |
| | Miami 3, Maryland 0 | Coral Gables, Fla. | Recap |
| 09/26/06 | Virginia 3, Virginia Tech 1 | Charlottesville, Va. | Recap | Gametracker |
| 09/27/06 | Duke 3, NC State 0 | Raleigh, N.C. | Recap |
| | Wake Forest 3, North Carolina 1 | Chapel Hill, N.C. | Recap | Gametracker | Webcast |
| 09/28/06 | Virginia 3, Boston College 1 | Chestnut Hill, Mass. | Recap |
| 09/29/06 | Clemson 3, Miami 1 | Clemson, SC | Recap | Gametracker | Webcast |
| | Florida State 3, Georgia Tech 2 | Atlanta, GA on FSN-South | Recap | Gametracker |
| | Virginia Tech 3, Maryland 1 | College Park, Md. | Gametracker | Recap |
| 09/30/06 | Virginia 3, Maryland 0 | College Park, Md. | Recap | Gametracker |
| | Clemson 3, Florida State 0 | Clemson, SC | Recap | Gametracker |
| | Duke 3, North Carolina 0 | Chapel Hill, N.C. | Gametracker | Recap |
| | Wake Forest 3, NC State 0 | Raleigh, N.C. | Recap |
| | Miami 3, Georgia Tech 1 | Atlanta, GA | Recap | Gametracker | Webcast |
| 10/01/06 | Boston College 3, Virginia Tech 2 | Chestnut Hill, Mass. | Recap |
| 10/03/06 | Boston College 3, Maryland 0 | Chestnut Hill, Mass. | Recap |
| 10/06/06 | Clemson 3, Boston College 0 | Chestnut Hill, MA | Recap |
| | Duke 3, Virginia 1 | Durham, N.C. | Recap | Live Stats |
| | Florida State 3, North Carolina 0 | Tallahassee, Fla. | Recap | Gametracker | Webcast |
| | Maryland 3, Georgia Tech 2 | College Park, MD | Recap | Gametracker |
| | Wake Forest 3, Virginia Tech 2 | Winston-Salem, N.C. | Recap |
| | Miami 3, NC State 1 | Coral Gables, Fla. | Recap |
| 10/07/06 | Wake Forest 3, Virginia 0 | Winston-Salem, N.C. | Recap | Gametracker |
| | Duke 3, Virginia Tech 0 | Durham, N.C. | Recap | Live Stats | Webcast |
| | Florida State 3, NC State 0 | Tallahassee, Fla. | Recap |
| 10/08/06 | Boston College 3, Georgia Tech 1 | Boston, Mass. | Recap |
| | Clemson 3, Maryland 0 | College Park, MD | Recap |
| | North Carolina 3, Miami 0 | Coral Gables, Fla. | Recap | Gametracker |
| 10/10/06 | Duke 3, Wake Forest 0 | Winston-Salem, N.C. | Gametracker | Recap | Webcast |
| 10/12/06 | Duke 3, Maryland 0 | Durham, NC | Recap | Live Stats | Webcast |
| 10/13/06 | Clemson 3, NC State 0 | Clemson, SC | Recap | Gametracker | Webcast |
| | Duke 3, Boston College 0 | Durham, N.C. | Recap | Live Stats |
| | Florida State 3, Virginia Tech 1 | Blacksburg, Va. | Recap | Live Stats |
| | Georgia Tech 3, North Carolina 0 | Atlanta, GA on FSN-South | Recap | Gametracker |
| | Virginia 3, Miami 0 | Charlottesville, Va. | Recap | Gametracker |
| | Wake Forest 3, Maryland 2 | Winston-Salem, N.C. | Recap | Gametracker |
| 10/14/06 | Clemson 3, North Carolina 0 | Clemson, SC | Recap | Gametracker |
| | Virginia Tech 3, Miami 1 | Blacksburg, Va. | Recap | Live Stats |
| | Wake Forest 3, Boston College 1 | Winston-Salem, N.C. | Recap | Gametracker | Webcast |
| | Georgia Tech 3, NC State 0 | Atlanta, GA | Recap | Gametracker | Webcast |
| | Florida State 3, Virginia 0 | Charlottesville, Va. | Recap | Gametracker |
| 10/17/06 | Clemson 3, Georgia Tech 0 | Clemson, SC | Recap | Webcast |
| | Miami 3, Florida State 2 | Tallahassee, Fla. on Sun Sports | Recap | Gametracker |
| 10/20/06 | Boston College 3, NC State 1 | Raleigh, N.C. | Recap |
| | Duke 3, Miami 0 | Coral Gables, Fla. | Gametracker | Recap |
| | Florida State 3, Wake Forest 0 | Tallahassee, Fla. | Recap | Gametracker |
| | Georgia Tech 3, Virginia Tech 0 | Blacksburg, Va. | Recap | Live Stats |
| | North Carolina 3, Maryland 0 | Chapel Hill, N.C. | Recap | Gametracker | Webcast |
| | Virginia 3, Clemson 1 | Charlottesville, VA | Recap | Gametracker |
| 10/21/06 | Virginia 3, Georgia Tech 2 | Charlottesville, Va. | Recap | Gametracker | Webcast |
| | Maryland 3, NC State 1 | Raleigh, N.C. | Recap |
| | North Carolina 3, Boston College 0 | Chapel Hill, N.C. | Gametracker | Webcast |
| 10/22/06 | Miami 3, Wake Forest 1 | Coral Gables, Fla. | Recap | Gametracker |
| | Duke 3, Florida State 0 | Tallahassee, Fla. on FSN-Florida | Recap |
| | Virginia Tech 3, Clemson 1 | Blacksburg, VA | Recap | Live Stats |
| 10/26/06 | Virginia Tech 3, North Carolina 1 | Chapel Hill, N.C. | Gametracker | Recap |
| 10/27/06 | Clemson 3, Wake Forest 0 | Clemson, SC | Recap | Gametracker |
| | Georgia Tech 3, Duke 2 | Atlanta, Ga. on FSN-South | Recap | Gametracker |
| | Maryland 3, Miami 0 | College Park, Md. | Recap |
| | Virginia 3, North Carolina 2 | Chapel Hill, N.C. | Recap | Gametracker |
| | Virginia Tech 3, NC State 0 | Raleigh, N.C. | Recap | Webcast |
| | Florida State 3, Boston College 0 | Chestnut Hill, Mass. | Recap |
| 10/28/06 | Duke 3, Clemson 2 | Clemson, S.C. | Gametracker | Recap |
| | Virginia 3, NC State 0 | Raleigh, N.C. | Recap |
| | Georgia Tech 3, Wake Forest 1 | Atlanta, Ga | Recap | Gametracker | Webcast |
| 10/29/06 | Miami 3, Boston College 1 | Chestnut Hill, Mass. | Recap | Webcast |
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